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Research from University of Bristol provides new data on metals.

Publication: Journal of Technology
Publication Date: 06-JAN-09
Format: Online
Delivery: Immediate Online Access

Article Excerpt
According to recent research from Bristol, the United Kingdom, "The binuclear cyclometalates [Pt2Cl2{2-CMe2C6H4P(C6H4(2-Pr-i))(2)}(2)] (1a) and [Pt2Cl2{2-CMe2C6H3(4-OMe)P(C6H3(2-Pr-i)(4-OMe))(2)}(2)] (1b) react with CHCl2CHCl2 to give the corresponding mononuclear phosphine-alkene chelates [PtCl2{2-CH2=CMeC6H4P(C6H4(2-Pr-i))(2)}] (2a) and [PtCl2{2-CH2=CMeC6H3(4-OMe)P(C6H3(2-Pr-i)(4-OMe))(2)}] (2b). The product 2a can also be formed directly from [PtCl2((NCBu)-Bu-t)(2)] and L-a in CHCl2CHCl2 or by addition...

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